Membrane and Water Treatment

Volume 16, Number 2, 2025, pages 77-86

DOI: 10.12989/mwt.2025.16.2.077

Evaluation of CO2 absorbent-based draw solution as draw solution for forward osmosis treatment of domestic wastewater

Sehyuk Ahn, Jieun Kim, Jeongkyun Yu, Hyunsup Jang, Sangyoup Lee, Ihn-Sup Han and Youngjin Kim

Abstract

This study investigates the feasibility of using sodium carbonate (Na2CO3) and sodium bicarbonate (NaHCO3), by-products of carbon dioxide (CO2) capture processes, as draw solutions (DSs) in forward osmosis (FO) systems. The primary objectives were to evaluate the basic performance of these DSs, analyze membrane fouling behaviors, and assess economic feasibility. The FO process demonstrated superior water flux performance with Na2CO3, attributed to its high osmotic pressure, followed by NaHCO3 and sodium chloride (NaCl). Fouling analysis revealed that Na2CO3 mitigates fouling due to its alkaline nature, which inhibits biofouling and scaling. Economic evaluations confirmed Na2CO3 as the most cost-effective DS, offering significant cost savings over NaHCO3 and NaCl at all recovery levels. These findings highlight the potential of Na2CO3 as a sustainable and efficient DS for wastewater treatment and other FO applications, emphasizing its compatibility with CO2 capture technologies.

Key Words

adsorbent; carbon capture; domestic wastewater; draw solution; forward osmosis

Address

Sehyuk Ahn and Ihn-Sup Han: School of Environmental Engineering, University of Seoul, Siripdae-gil 13, Dongdaemun-gu, Seoul, 02504, Republic of Korea Jieun Kim, Jeongkyun Yu and Youngjin Kim: Department of Environmental Engineering, College of Science and Technology, Korea University, 2511, Sejong-ro, Sejong, 30019, Republic of Korea Hyunsup Jang: Environmental Forensic Lab, Sungkyunkwan University, 2066, Seobu-ro, Jangan-gu, Suwon-si, Republic of Korea Sangyoup Lee: Institute of Conversions Science, Korea University, 145, Anam-ro, Sungbuk-gu, Seoul 02841, Republic of Korea