Geomechanics and Engineering

Volume 41, Number 2, 2025, pages 297-306

DOI: 10.12989/gae.2025.41.2.297

Experimental investigation on metakaolin/coal fly ash-based porous geopolymer grouting material for geotechnical applications

Karla Sierra , Philip Park , Chu-Lin Cheng , Yong Je Kim , Jae-Hoon Hwang , Bubryur Kim , Boo Hyun Nam , Jinwoo An

Abstract

This research investigates the development of a porous geopolymer cement grout for soil grouting applications, aiming to reduce carbon emissions associated with Portland cement while maintaining critical performance characteristics such as strength and permeability. Class F fly ash and metakaolin were used as aluminosilicate precursors, activated by sodium silicate and sodium hydroxide solutions. The addition of hydrogen peroxide served as a foaming agent to introduce porosity. Compressive strength and porosity were evaluated, with results showing that metakaolin significantly increased compressive strength due to its smaller particle size and higher reactivity. A higher molarity of sodium silicate enhanced strength by reducing the water-to-solid ratio, creating a denser matrix. In contrast, increasing hydrogen peroxide content raised porosity but reduced compressive strength by generating gas bubbles. X-ray diffraction (XRD) analysis revealed the ongoing formation of hydration products and a growing amorphous structure in the geopolymer matrix, contributing to strength development over time. The study concludes that the geopolymer grout can be optimized for a wide range of soil stabilization applications by adjusting material composition, foaming agent concentration, and activator molarity, offering an environmentally sustainable alternative to traditional cement grouts.

Key Words

coal fly ash; grouts; metakaolin; porous geopolymer; sinkhole remediation

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