In this experimental study, the reinforced concrete degradation subjected to chlorides penetration was investigated by electrochemical and physical-chemical tests at changes in coating depth. A comparative study was carried out on reinforced concrete specimens produced in the laboratory with different coating thicknesses. One of these specimens was kept as a control, while the two others were immersed in an aggressive environment (seawater) for a period of t = 4 years. The aim is to carry out an in-depth study of concrete and reinforcing steel in the test specimens' degradation, by analysing and quantifying the chloride-concrete-reinforcing steel interactions as a function of the thickness of the coating, while interpreting and justifying the phenomena underlying the degradation studied. The results of the tests carried out have provided a quantitative basis and an indepth understanding of the parameters of concrete degradation that cause a decrease in its mechanical strength, as well as the depassivation of steel through corrosion.